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The secret and illegal world of moonshining stretches all across Appalachia raking in a pretty penny for those who choose to shine. Moonshiners will go to unprecedented extremes in their efforts to hide their still sites and cloak their distribution networks, some can hide in plain sight. With new styles of shine being tested and sold there is a king's ransom waiting for those bold enough to grab it. But those who enforce the law are wise to shiner deceptions and more determined than ever to catch them red handed and in the act of making Moonshine. The day of reckoning may be around the corner, but don't sell the Moonshiners short. Each has a keen understanding of how to stay one step ahead of the law in their region, and in this ongoing cat and mouse game you never know who will end up in the trap.
With national supply chains disrupted, Mark and Digger unearth a ton of free ingredients, Tickle helps Josh build a submarine still farm and Mike designs a first-ever backwoods column still, perfect for endless runs of high-quality low-cost liquor.
When Josh lands a windfall of peaches, he and Tickle forge a peach brandy-making alliance. Mark and Digger's plans dry up when their surplus corn supply mysteriously disappears, and Mike and Jerry's column still spews ethanol vapor, causing a panic.
With his partner in quarantine, Digger has much more on the line than shine. Mike and Jerry's moonshine Frankenstein turns on its creators. After decades in the backwoods, mountain man Mark Rogers enlists his dad to run with him for the first time.
Mark and Digger deploy an old-world innovation to bring their barrel-aged reserves to market, while Tim attempts to make Tickle's CBD moonshine on a commercial scale. Josh puts himself at the mercy of the mountains' greatest peril -- a rookie shiner.
Tickle and the Laws unleash a 700-gallon run on a whisper-quiet steamer still. Mark and Huck traverse Appalachia's roughest terrain to run liquor with moonshine legend Jim Tom. Mike and Jerry engineer a high-tech solution to a backwoods problem.
Mark and Digger's plan to employ an out of work friend backfires on payday. Tim invents a low-cost way to make his first single-malt moonshine. With their backwoods column still cranking out liquor, Mike discovers Jerry isn't carrying his own weight.
Mark and Digger attempt oatmeal raisin shine for a high-flying Nashville customer; Mike and Jerry find themselves under the gun when they over deliver on proof to a biker gang; Mark and Huck forge a lifeline to old-time shiners deep in the mountains.
As Tickle and the Laws start a massive rye run, a mysterious tip results in too much of a good thing. Jerry gets rushed to the hospital and Mike finds himself shorthanded. Tim innovates a backwoods process for his single-malt shine.
After Mike asks the wrong shiner for help, Mark and Digger land a skilled new partner. On a mountain run, Mark and Huck nearly meet the barrel of a gun. Jerry attempts a comeback as a land sale forces him and Mike to abandon their column still site.
Facing more rye and apples than the Laws can run, Josh moves his steamer still to Virginia and Tickle adds smoke to the fire. Mark and Huck help Jim Tom turn cherries into shine. Mike and Jerry risk a huge run in the barn of an unsuspecting farmer.
A Mason jar shortage puts a lid on Mark and Digger's distribution plans. Mike and Jerry must return to land they've been warned off. Tim's scheme to repurpose a massive tank as an oversized pot still pushes his steam boiler to the breaking point.
Tickle and the Laws recruit Josh to build a winter-proof still site. Mountain man Mark converts a free load of sugar beets into high-proof moonshine. Mike and Jerry crack a few nuts to turn their column-distilled liquor into southern pecan liquor.
Mark and Digger find a solution to the jar shortage but the juice may not be worth the squeeze. Tim enlists Tickle's friend Howard to help recreate the first whiskey made in America. Mike and Jerry distill vodka from surplus restaurant supplies.
Mark and Digger invent a new recipe turning hundreds of jars of expired mandarin oranges into marketable liquor. Tickle and the Laws face headaches in their attempt to produce freeze-distilled apple liquor. Mike and Jerry make birch bark moonshine.
Tickle and the Laws invent a new recipe with master distiller Richard Landry. Mark and Digger crack their thousand jar problem while mashing in their most profitable run in years. Tim and Howard make a ceramic still to rediscover a colonial whiskey.
Trouble arises after Josh gains access to a cellar still site. Mark and Digger find a new way to cut costs and bayou shiner Richard makes medical moonshine.
A new limestone source helps Mark and Digger make Tennessee Whiskey while the Laws pull Tim back in to cross state lines for a key ingredient. Later, Richard makes moonshine from cotton candy.
Josh drives a tractor trailer full of stills across state lines to help Tickle and the Laws run two tons of malted corn. Mark and Digger christen their own secret Tennessee Whiskey distillery. Richard builds a copper Virginia-style submarine still.
Josh, Tickle and the Laws build a still farm the likes of which Virginia hasn't seen since the heyday of Amos Law. Jerry misses a day of work and Mike lets down his guard. Mark and Digger discover a rival moonshiner faces a reckoning with the law.
In the season finale, with eight stills running full tilt, Tickle enlists Mrs. Tickle to stash too much shine. Mark and Digger devise a way to age their Tennessee whiskey at sea. Tim gets drawn into an epic bootleg, while Mike and Jerry face the law.
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